Search for dissertations about: "process substitution"
Showing result 11 - 15 of 146 swedish dissertations containing the words process substitution.
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11. Asymmetric Synthesis and Mechanistic Studies on Copper(I)-Catalyzed Substitution of Allylic Substrates
Abstract : This thesis deals with the copper-catalyzed substitution of allylic substrates.In the first part of this thesis, the synthesis of a series of metallocenethiolates is described. The thiolates were examined as ligands in the enantioselective copper(I)-catalyzed γ-substitution of allylic acetates. READ MORE
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12. Quantum Chemical Studies of Aromatic Substitution Reactions
Abstract : In this thesis, density functional theory (DFT) is used to investigate the mechanisms and reactivities of electrophilic and nucleophilic aromatic substitution reactions (SEAr and SNAr respectively). For SEAr, the σ-complex intermediate is preceded by one (halogenation) or two (nitration) π-complex intermediates. READ MORE
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13. Development of Palladium-Catalyzed Transformations Involving η1-Allypalladium Species
Abstract : This thesis is focused on investigation of the structure, reactivity and isomerization reactions of η1-allylpalladium complexes, which are key intermediates in catalytic transformations. The first part of this thesis concerns the structure and reactivity of bis-allylpalladium complexes. READ MORE
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14. Sensorimotor transformations during grasping movements
Abstract : ‘Sensorimotor transformations’ are processes whereby sensory information is used to generate motor commands. One example is the ‘visuomotor map’ that transforms visual information about objects to motor commands that activates various muscles during grasping movements. READ MORE
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15. Livestock, feed production and land use – an environmental assessment
Abstract : The use of land for agriculture contributes substantially to today’s global environmental challenges such as climate change, water and land degradation and biodiversity loss. Today, about 38% of the ice-free land surface on earth is used as agricultural land, with about 75% of agricultural land used to produce feed for livestock. READ MORE