Search for dissertations about: "pseudo-C2"

Found 4 swedish dissertations containing the word pseudo-C2.

  2. 1. Flexibility – a tool for chirality control in asymmetric catalysis

    Author : Raivis Zalubovskis; Christina Moberg; Alexandre Alexakis; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; flexibility; symmetry; dissymmetry; asymmetric catalysis; chiral ligands; pseudo-C2; pseudo-CS; conformational study; rotation barrier; pyrrolidines; phospholanes; azepines; phosphepines; supramolecular; hydrogenation; allylic alkylation; silaboration; palladium; rhodium; nickel; platinum; iridium.; Organic chemistry; Organisk kemi;

    Abstract : This thesis deals with the design and synthesis of ligands for asymmetric catalysis: palladium catalyzed allylic alkylations, and rho-dium and iridium catalyzed hydrogenations of olefins. Chirally flexible phosphepine ligands based on biphenyl were synthesized and their properties were studied. READ MORE

  4. 2. Investigation of Symmetry and Electronic Effects in Asymmetric Palladium-Catalysed Allylic Substitutions

    Author : Robert Stranne; KTH; []
    Keywords : chiral ligands; catalysis; pseudo-C2; pseudo-meso; pyrrolidines; pyridines; phospholanes; 1; 1-binaphthylazepines; 1.1-binaphthylphosphepines; allylic substitution; palladium;

    Abstract : .... READ MORE

  5. 3. Investigations of New Biomimetic Transamination Systems and Inclusion Complexation with Cyclodextrins

    Author : Anders Hjelmencrantz; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; stereochemis; bicyclooctanes.Transamination; complexation; cyclodextrins; proton transfer; hydride transfer; stereochemistry; Transamination; Organic chemistry; Organisk kemi;

    Abstract : Two new transamination systems are described. The first example is a dibenzo[a,d]- cycloheptene containing system, designed to accomplish a [1,3]-hydride transfer. Several catalysts have been examined for this purpose. tris-Pentafluorophenyl borane was found to be the most efficient catalyst. READ MORE

  6. 4. Bispyridylamides as ligands in asymmetric catalysis

    Author : Oscar Belda de Lama; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; chiral ligand; pyridine; amide; allylic alkylation; enantioselective; cyanation; ring-opening; chiral Lewis acid;

    Abstract : This thesis deals with the preparation and use of chiralbispyridylamides as ligands in metal-catalyzed asymmetricreactions. The compounds were prepared by amide formation usingdifferent coupling reagents. READ MORE