Search for dissertations about: "pseudo-CS"

Found 2 swedish dissertations containing the word pseudo-CS.

  2. 1. Flexibility – a tool for chirality control in asymmetric catalysis

    Author : Raivis Zalubovskis; Christina Moberg; Alexandre Alexakis; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; flexibility; symmetry; dissymmetry; asymmetric catalysis; chiral ligands; pseudo-C2; pseudo-CS; conformational study; rotation barrier; pyrrolidines; phospholanes; azepines; phosphepines; supramolecular; hydrogenation; allylic alkylation; silaboration; palladium; rhodium; nickel; platinum; iridium.; Organic chemistry; Organisk kemi;

    Abstract : This thesis deals with the design and synthesis of ligands for asymmetric catalysis: palladium catalyzed allylic alkylations, and rho-dium and iridium catalyzed hydrogenations of olefins. Chirally flexible phosphepine ligands based on biphenyl were synthesized and their properties were studied. READ MORE

  4. 2. Symmetry in Asymmetric Catalysis and Hydrogen Bond-Based Self-Assembly : Synthesis and Investigations

    Author : Yutang Li; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; bissalen; asymmetric ring opening; pseudo-Cs; hydrogen bonding; self-assembly; C3 symmety; trilactam; scXRD; solubility; epoxidation; rearrangement; Baeyer-Villiger reaction; transition state; DFT calculation; cyclodextrin; polyethylene glycol; amphiphilicity;

    Abstract : The thesis elaborates on four different projects focusing on synthesizing symmetry-related molecules and investigating their performance as catalysts for asymmetric catalysis or as monomers for hydrogen bond-based self-assembly.Chapter 2 describes a new method to desymmetrize a meso-ligand. READ MORE