Search for dissertations about: "reaction rate constant"

Showing result 1 - 5 of 75 swedish dissertations containing the words reaction rate constant.

  2. 1. Chemometric methods for analysis of spectroscopic data from batch process monitoring

    Author : Erik Furusjö; KTH; []
    Keywords : in situ spectroscopy; reaction monitoring; organic synthesis; solubility; crystallization; multivariate calibration; curve resolution; kinetic model; reaction rate constant; activation energy; target testing; bootstrap;

    Abstract : Understanding of a process is essential for processdevelopment, optimisation and scale-up. In situ spectroscopy isan attractive measurement technique that can increase processunderstanding, since samples need not be retrieved from theprocess mixture. READ MORE

  4. 2. On the Influence of Mixing and Scaling-Up in Semi-Batch Reaction Crystallization

    Author : Marika Torbacke; KTH; []
    Keywords : reaction crystallization; precipitation; benzoic acid; macromixing; mesomixing; micromixing; semi-batch; loop reactor; backmixing; colour experiments; scaling-up;

    Abstract : Semi-batch crystallization experiments have been performedboth in a loop reactor and in stirred tank reactors.Hydrochloric acid was fed to a stirred solution of sodiumbenzoate, and benzoic acid immediately formed. Benzoic acid isformed in excess of the solubility making the solutionsupersaturated.The loop reactor is U-shaped. READ MORE

  5. 3. Reaction-Diffusion kinetics of Protein DNA Interactions

    Author : Anel Mahmutovic; Johan Elf; David van der Spoel; Pieter Rein ten Wolde; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; umbrella sampling; molecular dynamics; RDME; PDE; sliding; intersegment transfer; hopping; sterics; intersegment transfer; Biology with specialization in Molecular Biotechnology; Biologi med inriktning mot molekylär bioteknik;

    Abstract : Transcription factors need to rapidly find one specific binding site among millions of nonspecific sites on the chromosomal DNA. In this thesis I use various aspects of reaction-diffusion theory to investigate the interaction between proteins and DNA and to explain the searching, finding and binding to specific operator sites. READ MORE

  6. 4. Quantum dynamical effects in complex chemical systems

    Author : S. Karl-Mikael Svensson; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Quantum dynamics; Radiative association; Classical Wigner method; Feynman path integral; Reaction rate constants; Wigner phase space;

    Abstract : When using mathematical models to computationally investigate a chemical system it is important that the methods used are accurate enough to account for the relevant properties of the system and at the same time simple enough to be computationally affordable. This thesis presents research that so far has resulted in three published papers and one unpublished manuscript. READ MORE

  7. 5. Radiation Induced Oxidative Dissolution of UO2

    Author : Ella Ekeroth; Mats Jonsson; Bernd Grambow; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; radiation; radiolysis; UO2; spent nuclear fuel; radicals; oxidants; reductants; rate constants; dissolution; H2O2; H2; Nuclear chemistry; Kärnkemi;

    Abstract : Sammanfattning Denna doktorsavhandling berör oxidativ upplösning av UO2 (som modellsubstans för utbränt kärnbränsle) orsakad av radiolys av vatten samt effekten av H2 på denna denna process. Hastighetskonstanter för oxidation av UO2-pulver med olika oxidanter såsom H2O2 har bestämts experimentellt. READ MORE