Search for dissertations about: "rhenium"
Showing result 1 - 5 of 10 swedish dissertations containing the word rhenium.
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1. Homogeneous and Heterogeneous Cluster-Based Catalysts for Asymmetric Reactions
Abstract : Synthesis and characterization of new transition metal carbonyl clusters has been undertaken, and evaluation of the new clusters to act as catalysts/catalysts precursor in asymmetric reactions has been carried out. The catalytic hydrogenation of tiglic acid under relatively mild conditions, using diastereomeric clusters of the general formula [(µ-H)2Ru3(µ3-S)(CO)7(µ-1,2-L)] (L= chiral diphosphine of the ferrocene-based Walphos and Josiphos families) as catalysts, reveal different catalytic behavior in terms of conversion and enantioselectivity. READ MORE
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2. Methods for Asymmetric Olefination Reactions; Development and Application to Natural Product Synthesis
Abstract : This thesis deals with the development and application of methods for asymmetric olefinations, in particular Horner-Wadsworth-Emmons (HWE) reactions, in the synthesis of certain natural products. Relying on asymmetric HWE reactions to access key building blocks, two natu-ral products, pyranicin and pyragonicin, were synthesized from common late intermediates. READ MORE
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3. Alkoxide complexes of rhenium, niobium and tantalum
Abstract : This thesis describes two major methods for preparation of new mono-, bi- and trimetallic complexes on the basis of Rhenium, Niobium and Tantalum: (1) - the electrochemical method for the synthesis of Re4O4(OEt)12 and (2) - the interaction of Rhenium heptoxide, Re2O7, with alkoxo-derivates of Niobium and/or Tantalum, M2(OR)10 for the synthesis of bi- and trimetallic complexes of common formula (M1-xM'x)4O2(OR)14(ReO4)2 (M = Nb; M' = Ta; R = Me, Et), where x = 0–1. The structures of these complexes were determined by single-crystal X-ray diffraction. READ MORE
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4. Alkoxide complexes of rhenium - precursors of nanomaterials
Abstract : The thesis presents the work constituted by two major parts: (1) – synthesis of new mono-, bi- and trimetallic complexes based on Re, Nb and Ta and their physical-chemical characterization, and (2) – preparation of nanostructural functional materials derived from these complexes. The precursors and materials were characterized by FTIR, NMR, MS, SEM–EDS, TEM and X-ray diffraction. READ MORE
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5. Radiolabeling and Biotinylation of Internalizing Monoclonal Antibody Chimeric BR96: Potential Use for Extracorporeal Immunoadsorption
Abstract : In this thesis, methodology of radiolabeling and simultaneous biotinylation for internalizing monoclonal antibody (MAb) chimeric BR96 (chiBR96) have been investigated by using three element groups of potential therapeutic radionuclides iodine, indium and rhenium, and their different labeling methods. The biodistribution and kinetics of biotinylated and radiolabeled chiBR96 have been studied in colon carcinoma isografted rats. READ MORE
