Search for dissertations about: "sigmatropic rearrangement"

Found 5 swedish dissertations containing the words sigmatropic rearrangement.

  2. 1. Lewis Acid Mediated [2,3]-Sigmatropic Rearrangement of Allylic Ammonium Ylides

    Author : Jan Blid; KTH; []
    Keywords : Sigmatropic rearrangement; Lewis acid; Ammonium ylide; NMR spectroscopy; Density functional calculations;

    Abstract : This thesis describes a Lewis acid mediated[2,3]-sigmatropic rearrangement of various allylic ammoniumylides. Several Lewis acids are investigated and BBr3 and BF3are established to be the Lewis acids providing the highestconversion of the starting allylic amines. READ MORE

  4. 2. Asymmetric [2,3]-Sigmatropic Rearrangement of Allylic Ammonium Ylides

    Author : Jan Blid; Peter Somfai; James C. Anderson; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; asymmetric; [2; 3]-sigmatropic rearrangement; allylic amine; ammonium ylide; Lewis acid; enantioselective; boron; phosphazene base; NMR spectroscopy; DFT-calculations; Organic chemistry; Organisk kemi;

    Abstract : The thesis describes the realization of an asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines. It is divided into two parts; the first part deals with the development of a Lewis acid-mediated [2,3]-sigmatropic rearrangement and the second the asymmetric version thereof. READ MORE

  5. 3. Synthesis and [3,3]-Sigmatropic Rearrangement of Vinylaziridines

    Author : Ulf Lindström; Torbjörn Frejd; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Abstract : A general synthetic route from vinylepoxides to vinylaziridines via 1,2-amino alcohols was developed. The 1,2-amino alcohols were obtained from a stereospecific and regioselective aminolysis of vinylepoxides. The synthetic scope of the aminolysis could be expanded by the use of a microwave-assisted protocol. READ MORE

  6. 4. Metal‐Free Arylations of Oxygen and Nitrogen Nucleophiles : Applications of Diaryliodonium Salts

    Author : Elin Stridfeldt; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; arylation; aryloxyamines; cyclization; diaryliodonium salts; O-aryloximes; sigmatropic rearrangement;

    Abstract : This thesis concerns development of new methods for metal‐free arylations in organic synthesis. The protocols discussed in the thesis are based on a class of hypervalent iodine compounds called diaryliodonium salts. These reagents are known to transfer aryl moieties to suitable nucleophiles. READ MORE

  7. 5. New synthetic routes to azaspiro alkaloids : Applications to the synthesis perhydrohistrionicotoxin

    Author : Lars Hagberg; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Abstract : Perhydrohistrionicotoxin, 1, is related to a family of alkaloids which display pharmacologically interesting properties. The thesis deals with development of new methods for the chemical synthesis of such alkaloids, and is divided into three parts according to the different approaches. READ MORE