Search for dissertations about: "single-crystal X-ray investigations"

Showing result 1 - 5 of 16 swedish dissertations containing the words single-crystal X-ray investigations.

  1. 1. Protective and Nanoporous Alumina Films Studied in situ by X-ray and Electrochemical Methods

    Author : Jonas Evertsson; NanoLund: Centre for Nanoscience; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; XRR; XPS; XRF; GTSAXS; EIS; Synchrotron Radiation; Native oxide; Anodization; Anodic aluminum oxide; Nanoporous aluminum oxide; Single crystal; Aluminum alloys; in situ; Fysicumarkivet A:2018:Evertsson;

    Abstract : In this thesis, the studies of native and anodic oxides on both aluminum model single crystal surfaces as well as on aluminum alloys found in applications are presented. The focus has been on the characterization in situ as the oxide is growing by an electrochemical process called anodization. READ MORE

  2. 2. High pressure structural investigations using single crystal techniques : influence of pressure on Jahn-Teller distorted alkali manganese fluorides

    Author : Stefan Carlson; Stefan Werner; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; strukturkemi; Structural Chemistry;

    Abstract : The results from high-pressure single-crystal X-ray diffraction studies of some ternary sodium transition metal fluorides are presented. The structures of NaMnF4, Na2MnF5, Na3MnF6 and Na3ScF6 have been investigated at high pressures, and in connection with these studies the Na5Mn3F14 structure has been investigated at ambient pressure. READ MORE

  3. 3. Surface Studies of Model Systems relevant for Pd and Ag Catalysts

    Author : Natalia Martin; Synkrotronljusfysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; High Pressure X-ray Photoelectron Spectroscopy; X-ray Photoelectron Spectroscopy; alumina; Ag; NiAl; Pd; catalysis; model system; Surface X-ray Diffraction; Low Energy Electron Diffraction; Scanning Tunneling Microscopy; Fysicumarkivet A:2014:Martin;

    Abstract : This PhD thesis reports on investigations of the atomic scale structure of model catalysts relevant for the catalytic oxidation of CO and methane over Pd, and NOx reduction over silver-alumina, important reactions in automotive catalysts. By using complementary experimental techniques such as X-ray Photoelectron Spectroscopy, High Pressure X-ray Photoelectron Spectroscopy, Surface X-ray Diffraction, Low Energy Electron Diffraction, Infrared Spectroscopy, and Scanning Tunneling Microscopy, combined with theoretical calculations, the work presented in this thesis aims at an atomistic characterization of the active sites for silver-alumina and Pd model catalysts which may help to the design of new and improved catalysts. READ MORE

  4. 4. Crystal structure studies of a new series of molybdovanadate polyanions and some related vanadates

    Author : Arne Björnberg; Umeå universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; isopolyvanadates; molybdovanadate polyanions; single-crystal X-ray investigations; ESR spectroscopy; heteropoly blues;

    Abstract : The determination of complexes formed in weakly acidic aqueous solutions containing pentavalent vanadium as well as hexavalent molybdenum has proved diffi cui t due to slow equilibria and 1 imi ted sol ubi 1 i ty of especially the vanadium species. The formation of several different polynuclear complexes with a very varied molybdenum/vanadium ratio also complicates the interpretation of Potentiometrie data. READ MORE

  5. 5. Chirality in Crystal Engineering

    Author : Krister Larsson; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; networks; 2; coordination chemistry; crystal engineering; 10; 3-nets; hydrogen bonding; 2 -biimidazole; single crystal X-ray diffraction; bis-chelating ligands; chirality;

    Abstract : Crystal engineering combines supramolecular chemistry with solid state chemistry. The goal is to make molecular entities assemble into predefined structures with specific properties. At the same time much research is focused on the understanding of the intermolecular interactions governing the crystallisation process. READ MORE