Search for dissertations about: "spectroelectrochemistry"

Showing result 6 - 10 of 14 swedish dissertations containing the word spectroelectrochemistry.

  2. 6. Conducting Redox Polymers for Electrical Energy Storage : Backbone - Substituent Interactions in Quinone Polypyrrole Model Systems

    Author : Christoffer Karlsson; Martin Sjödin; Petr Novák; Uppsala universitet; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Organic energy storage; Hydroquinone polymers; Functionalized polypyrrole; Spectroelectrochemistry; Electrochemical quartz crystal microbalance; In situ conductivity;

    Abstract : Organic electrical energy storage (EES) is a growing field of research that is expected to play an important role in the future, as the need for sustainable EES increases. Conducting redox polymers (CRPs), i.e. conducting polymers with incorporated redox active moieties e. READ MORE

  4. 7. Functional and Modular As=C and P=C Group Motifs

    Author : Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

    Abstract : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. READ MORE

  5. 8. Development of Second and Third Generation Bioelectronics

    Author : Federico Tasca; Biokemi och Strukturbiologi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; flow injection analysis; amperometric biosensor; mediated electron transfer; direct electron transfer; tryptophan repressor-binding protein; diaphorase; pyranose oxidase; cellobiose dehydrogenase; pyranose dehydrogenase; biofuel cell; spectroelectrochemistry; single wall carbon nanotubes; bioelectronics.;

    Abstract : The field of research dealing with the integration of biomolecules with electronic elements to form functional devices is called ‘‘bioelectronics’’. Bioelectronics based on mediated electron transfer (MET) between the biological element and the electrodes are designated as “second generation” while the one based on direct electron transfer (DET) is specified as “third generation”. READ MORE

  6. 9. Heterogeneous electron transfer studies with ligninolytic redox enzymes and living bacteria. Applications in biosensors and biofuel cells

    Author : Vasile Coman; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; cellobiose dehydrogenase; direct electron transfer; mediated electron transfer; self-assembled monolayer; flow injection analysis; amperometric biosensor; E. coli; succinate:quinone reductase; biofuel cell; B. subtilis; whole-cell biosensor;

    Abstract : The catalytic properties and the inter-domain electron transfer of cellobiose dehydrogenase (CDH) from the ascomycete fungus Myriococcum thermophilum adsorbed on graphite and thiol (SAM) modified gold electrodes were investigated using cyclic voltammetry, flow injection amperometry and UV-Vis spectroelectrochemistry. The fabrication and characterisation of a noncompartmentalised, mediator and cofactor free glucose–oxygen biofuel cell well-operating in glucose-containing buffers and human blood serum was performed. READ MORE

  7. 10. Dyes and their adsorption onto nanocrystalline TiO2 electrodes : Synthesis, characterisation and applications

    Author : Viviane Aranyos; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Abstract : The syntheses of two type of dyes (phthalocyanine and ruthenium tris-bipyridyl) are presented here. Their characterisation involves the use of cyclic voltammetry, NMR- and UV-visible spectroscopy. Once adsorbed on nanocrystalline TiO2 electrodes, their electrochemical, spectroelectrochemical and photoelectrochemical properties were investigated. READ MORE