Search for dissertations about: "thioether"

Showing result 1 - 5 of 22 swedish dissertations containing the word thioether.

  2. 1. Coordination of Phosphine-Thioether Ligands to Low-valent Metal Centers

    Author : Roger Persson; Kemisk fysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; polynuclear metal complexes; fluxional behavior; cluster; thioether; phosphine; crystal structure; sulfur; triosmium;

    Abstract : The reactivity of the phosphine-thioether ligands bis(2-diphenylphosphino) ethylthio)ethane (PSSP), bis(2-(diphenylphosphino) ethyl)sulfane (PSP), PPh2CH2CH2SMe (PS), PPh2(o-C6H4SMe (PortoS), and PPh(o-C6H4SMe)2 (PSS) towards low-valent carbonyl clusters has been studied. In all structurally characterized clusters, the ligand donor atoms are terminally coordinated. READ MORE

  4. 2. Naphthoxylosides Investigations into glycosaminoglycan biosynthesis

    Author : Mårten Jacobsson; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; proteoglycan; Organic chemistry; nucleophilic aromatic substitution; thioether; glycosaminoglycan; xylosides; naphthoxylosides;

    Abstract : Glycosaminoglycans (GAGs) are members of a family of polysaccharide structures consisting mostly of repeating disaccharide units. Most GAGs are attached to specific serine residues in proteins to form proteoglycans (PGs). READ MORE

  5. 3. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes

    Author : Tiesheng Shi; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; thiol; l-methionine; maleic acid; carboxylic acid; thioether; platinum IV ; palladium II ; linear free energy relationship; volumes of activation; structure-reactivity correlation; reduction; substitution; equilibria; kinetics; mechanism; glutathione; Animal physiology; Djurfysiologi;

    Abstract : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. READ MORE

  6. 4. Lignin-Based Thermosets with Tunable Mechanical and Morphological Properties : A Study of Structure-Property Relationships

    Author : Iuliana Ribca; Mats Johansson; Martin Lawoko; Stephan V. Roth; Mika Sipponen; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Softwood; hardwood; technical lignin; solvent fractionation; allylation; thiol-ene thermosets; thioether linkage; wide-angle X-ray scattering; π-π stacking interactions; Barrträ; lövträ; tekniskt lignin; lösningsmedelsfraktionering; allylering; tiol-en-härdplaster; tioeterbindning; vidvinkelröntgenspridning; π-π staplingsinteraktioner; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Abstract : Nowadays, there is an urgent need to decrease our dependence on fossilresources and shift towards the use of renewable resources for advancingsustainable development. Utilizing renewable and bio-based raw materials,such as lignocellulosic biomass, for designing new materials is a promisingapproach to promote this objective. READ MORE

  7. 5. Exploring different thermoplastics from lignocellulosic building blocks and monomers

    Author : Olivier Bonjour; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Biobased plastics; Biobased polymers; Polymethacrylates; Polycarbonates; Polyesters; Poly beta-thioether ester s; Chemical recycling; Biobased plastics; Biobased polymers; Polycarbonates; Polymethacrylates; Poly beta-thioether ester s; Polyesters; Chemical recycling;

    Abstract : The need to replace conventional fossil-based plastics is becoming more imperative. As climate change is more visibly affecting our society, employing non-sustainable resources to produce plastics is aggravating the problem. READ MORE