District Heating-driven Membrane Distillation for Water Purification in Industrial Applications

Abstract: Domestic and industrial water demands are growing globally due to population growth and rapid economic development, placing increasing strains on water resources. Wastewater effluents generated from these and other activities impact the environment and are thus subject to tightening regulation. The focus of research and development in water treatment processes aims at both pollutant removal efficiency and cost of purification.Membrane distillation (MD) is a developing thermally driven technology capable of achieving extremely high environmental performance utilizing renewable energy sources to a high degree. District heating networks, and in particular those driven by biomass, represent an ideal heat supply for MD systems.This thesis presents a technoeconomic assessment of district heating driven MD for water purification in selected industrial applications. The study covers analysis of MD separation performance and the related costs from different district heating integration scenarios. The analyses are based on three types of semi-commercial MD modules, with experiments conducted at laboratory and pilot scales. The case studies include pharmaceutical residue removal from effluents of municipal wastewater treatment plant, wastewater purification in pharmaceutical industry, and ethanol concentration in bioethanol production plant. Full-scale simulation studies were carried out for the identified case studies based on the experimental data obtained from MD module along with process information gathered from the industries. Results from the pharmaceutical residue removal pilot trials showed very good to excellent separation efficiency for 37 compounds at feed concentrations ranging from ng/L to mg/L. From alcohol-water feeds, ethanol concentrations were increased from 5% to nearly 90%. Simulation studies revealed that district heating integration of MD systems is feasible. Costs per unit volume of purified water are higher than competing technologies, however the configurations enable enhanced environmental performance that would be difficult to achieve otherwise.