Search for dissertations about: "hypervalent iodine chemistry"

Showing result 1 - 5 of 19 swedish dissertations containing the words hypervalent iodine chemistry.

  2. 1. Development and Applications of Hypervalent Iodine Compounds : Powerful Arylation and Oxidation Reagents

    Author : Nazli Jalalian; Berit Olofsson; Viktor V. Zhdankin; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; hypervalent iodine compounds; diaryliodonium salts; oxidation; Koser s reagent; arylation; phenols; diaryl ethers; chemoselectivity; organisk kemi; Organic Chemistry;

    Abstract : The first part of this thesis describes the efficient synthesis of several hypervalent iodine(III) compounds. Electron-rich diaryliodonium salts have been synthesized in a one-pot procedure, employing mCPBA as the oxidant. Both symmetric and unsymmetric diaryliodonium tosylates can be isolated in high yields. READ MORE

  4. 2. Synthetic and Mechanistic Studies with Iodine(III) Reagents

    Author : Ester Maria Di Tommaso; Berit Olofsson; Marcos Suero; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; hypervalent iodine chemistry; organic synthesis; mechanistic studies; DFT; photocatalysis; Organic Chemistry; organisk kemi;

    Abstract : This thesis describes the development of metal-free transformations and mechanistic studies on the reactivity of two classes of hypervalent iodine reagents: diaryliodonium salts and vinylbenziodoxolones (VBX). Recently, they have been recognized as valuable synthetic reagents with broad applicability in organic synthesis. READ MORE

  5. 3. Bifunctionalization of Small Organic Molecules Based on Fluorine Incorporation

    Author : Marvin Lübcke; Kálmán Szabó; Ryan Gilmour; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; fluorination; fluorocyclization; fluorine chemistry; trifluoromethylthiolation; rhodium-catalysis; organocatalysis; asymmetric synthesis; hypervalent iodine; multicomponent reaction; bifunctionalization; diazo compounds; organisk kemi; Organic Chemistry;

    Abstract : The dissertation work that is summarized in this thesis describes novel syntheses of organofluorine compounds with a broad coverage of different fluorine-containing motifs.Chapter 2.1 covers works on the exploration of new trifluoromethylthiolating reactions of diazocarbonyl compounds. READ MORE

  6. 4. Enols and Allylic Alcohols as Building Blocks in Synthetic Organic Chemistry : Experimental and Theoretical Studies

    Author : Alba Carretero Cerdán; Belén Martín‐Matute; Shu-Li You; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Base catalysis; Ion-pair; Isomerization; MOFs; Hypervalent Iodine III ; DFT; Organic Chemistry; organisk kemi;

    Abstract : The present thesis describes computational and experimental studies used to drive the reactivity of allylic and enol substrates towards new transformations. These synthetic methods give access to a number of organic molecules that may serve as important moieties in synthetic organic chemistry. READ MORE

  7. 5. Hypervalent Iodine Reagents in Metal-Free Arylations and Vinylations : Investigation of Suitable Coupling Partners and Synthesis of New Reagents

    Author : Elin Stridfeldt; Berit Olofsson; Zoltán Novák; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Diaryliodonium Salts; Benzofurans; Aryl Ethers; Secondary Amides; Vinylbenziodoxolones; organisk kemi; Organic Chemistry;

    Abstract : This thesis concerns the development of metal-free reactions to obtain carbon-heteroatom and carbon-carbon bonds. This is achieved by transferring carbon ligands from hypervalent iodine reagents to suitable nucleophiles. READ MORE