Lignin nanoparticles for photonic crystals and photothermal films

Abstract: The development of sustainable materials from biobased resources is essential due to environmental concerns posed by fossil-based materials. Lignin is a chemically complex biopolymer that exists in woody tissues of vascular plants. Lignin has many useful properties such as antioxidant activity, thermal stability, UV-absorbance, rigidity and so on. However, an inherent challenge of lignin relates to its complex molecular structures and poor solubility in water and common solvents. One strategy to utilize lignin is to fabricate lignin nanoparticles (LNP) that produce colloidally stable dispersions in water. This thesis aims to develop LNP-based materials which can be used in photonic crystals and photothermal films towards energy-efficient functional materials.The first part of the thesis focused on elucidation of the phenomena occurring during centrifugation-assisted assembly of LNP-photonic crystal (L-PC). L-PC with rainbow coloration or separate colors were produced by controlling the polydispersity index (PDI), particle size (150 to 240 nm), and assembly of LNPs. In a follow-up work, an improved method was developed to increase the yield of L-PCs. The effects of factors such as initial lignin concentration, and dilution time on the particle size and PDI of formed LNPs were studied. Empirical models were established to predict the size of LNPs and successfully used to control the resulting color of L-PCs. Moreover, the nanostructure of L-PCs was investigated. To harness lignin’s ability to absorb solar energy (light wavelength: 250–2500 nm), LNP-based composite films and coatings with photothermal performance were developed in the second part of the thesis. LNP-chitosan films and coatings were prepared and applied to indoor heat management. The LNPs content was adjusted from 10 to 40 wt%. By incorporating LNPs, the mechanical strength and photothermal properties of the films were improved compared to the pure chitosan film. Moreover, LNP-silver-chitosan (CC-Ag@LNP) films were prepared by using LNPs as a reducing agent. Silver ions were reduced on the surface of LNPs with UV-light assistance, and the hybrid nanoparticles were used to prepare films by casting. The CC-Ag@LNP films exhibited improved wet-strength and exhibited antibacterial performance against Escherichia coli (sterilization effect > 99.9%).Overall, this thesis contributes to both the fundamental insight in lignin aggregation to colloidal particles and showcases ways to control their assembly and incorporation into macroscopic materials with added functionality.